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How to Reduce the Carbon Footprint of Steam Methane Reforming With Biogas

Biogas can lower the lifecycle footprint of steam methane reforming, but the outcome depends on methane losses, plant heat and efficiency, capture coverage, and the lifecycle boundary used.
From TheFinanceBase Team5 min to read
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Using biogas or upgraded biogas (biomethane) as SMR feedstock can reduce hydrogen’s lifecycle greenhouse-gas impact, but it does not automatically make the hydrogen carbon neutral. The result depends on how the gas is made, methane losses and upgrading energy, the reformer’s efficiency and heat supply, and which emissions the calculation includes. The most credible reductions combine verified low-leakage feedstock with efficient operation, control of operating losses, and carbon capture assessed across the relevant process streams.

How does biogas-based steam methane reforming work?

Steam methane reforming (SMR) reacts methane with high-temperature steam over a catalyst to produce hydrogen and carbon monoxide. A subsequent water-gas shift reaction converts carbon monoxide and steam into additional hydrogen and carbon dioxide; pressure-swing adsorption then separates hydrogen from carbon dioxide and other impurities. The U.S. Department of Energy describes steam temperatures of 700°C–1,000°C and pressures of 3–25 bar. Because the reaction is endothermic, the plant must also supply heat, commonly by burning fuel in a reformer furnace.

That creates two important carbon pathways to assess: carbon in the methane feed that becomes process CO2, and emissions from the fuel used to supply heat. A lower-carbon feedstock does not by itself eliminate furnace emissions. Biogas may be used directly where its composition and the plant design permit, or upgraded to biomethane before delivery; these are different supply chains and should be accounted for separately.

What determines whether biogas lowers the footprint?

Feedstock origin and methane losses

Biogenic carbon in the gas is not the same as zero lifecycle emissions. Digestion or landfill-gas collection, upgrading, storage, transport, and delivery can involve methane losses and energy use. Because methane escaping before combustion can materially affect the climate result, a renewable label alone is not enough to establish a benefit. The European Commission’s Joint Research Centre 2024 report addresses measurement, mitigation, and accounting for methane emissions in EU biogas and biomethane supply chains; its geographic focus is the EU.

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Plant efficiency and heat supply

Less energy and methane consumed per kilogram of hydrogen generally means lower emissions per kilogram. Heat integration and waste-heat recovery can reduce energy demand, while minimizing unreacted methane can reduce losses. Any comparison also needs to identify the furnace fuel or other heat source: emissions from supplying reformer heat remain relevant even when feed methane is biogenic.

Capture coverage and operating conditions

Carbon capture claims depend on what is included: concentrated process CO2, reformer furnace flue gas, and carbon-containing purification off-gas are not interchangeable streams. The capture rate should state its boundary and operating conditions, and account for reduced capture during flexible operation, startup, shutdown, or outages. The UK Environment Agency’s guidance for hydrogen production and CO2-capture plant designs within its scope says to design for an overall capture rate of at least 95%, averaged over an extended period; a lower rate needs justification. This is UK guidance for its defined scope, not a universal legal requirement or a claim about achieved performance at every plant.

What do published estimates say?

The figures below come from different studies and scenarios. They use different system boundaries and assumptions, so they are not a like-for-like ranking of feedstocks or plants.

Study or scenario Reported result What the result represents
Energy Reports study authors, 2022 9.35 kg CO2e/kg H2 Estimated direct-emissions impact for 33 U.S. SMR hydrogen facilities using facility-level emissions data.
Energy Reports study authors, 2022 11.2 kg CO2e/kg H2 Estimate after the study included upstream emissions in its lifecycle boundary.
Energy Reports study authors, 2022 5.9% and 11.1% lower impact Modeled average global-warming impact reductions when hydrogen-production efficiency increased by 5% and 10%, respectively.
Energy Reports study authors, 2022 53.7% lower impact Modeled reduction for replacing natural-gas feedstock with biomethane; this scenario-specific result is not a universal estimate for all biomethane or plants.
Energy Reports study authors, 2022 68.2% lower impact Modeled landfill-gas feedstock pathway, distinct from the study’s biomethane scenario.
Energy Reports study authors, 2022 78.1% lower impact Modeled biomass-gasification pathway, not a result for biogas reforming.
International Journal of Hydrogen Energy indexed study record, 2016 5.59 kg CO2-eq/kg H2 Modeled biogas-to-hydrogen system, described as about half the lifecycle emissions of the conventional SMR systems used for comparison. The record attributes results partly to displaced-fertilizer credits from digestate and recycling credits, so the number cannot be compared directly with other studies without aligning boundaries and allocation.
Politecnico di Milano study, 2024 Up to 76% of biogenic carbon recovered; up to −9 kg CO2/kg H2 Modeled outcomes for an electrified biogas-reforming configuration with CO2 separation, not measured plant results or a general commercial guarantee.

The estimates show why the functional unit and boundary matter. Direct facility emissions and lifecycle emissions answer different questions; figures per kilogram of hydrogen should not be treated as equivalent unless they cover comparable emissions and use comparable allocation methods.

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Which changes can reduce emissions at a plant?

  1. Verify the gas supply. Document whether the input is raw biogas, upgraded biomethane, or landfill gas; identify its origin and upgrading route; and measure or credibly estimate methane emissions from production through delivery. Include the energy used for upgrading and transport. The EU JRC’s 2024 guidance is relevant to EU supply chains, while other locations require appropriate local data and methods.
  2. Improve hydrogen-production efficiency. Track energy and methane use per unit of hydrogen, reduce unreacted methane, integrate heat, and recover usable waste heat. The Energy Reports study’s modeled efficiency scenarios show that efficiency can change estimated climate impact, while the UK Environment Agency directs scoped plant designs to maximize energy and process efficiency.
  3. Include the heat source in the emissions inventory. Account for furnace fuel or other heat inputs alongside feedstock-related process emissions. A feedstock switch cannot substantiate a low plant footprint if the heat supply is omitted from the stated boundary.
  4. Assess capture across relevant streams. Evaluate process CO2, furnace flue gas, and carbon-containing purification off-gas, and state which streams are covered by any capture-rate claim. For plants within its scope, UK Environment Agency guidance calls for a design target of at least 95% overall capture averaged over an extended period and for minimizing losses during flexible operation.
  5. Reduce routine and variable-operation losses. Minimize routine venting and flaring of methane and hydrogen, and include emissions during startup, shutdown, flexible operation, and outages rather than relying only on steady-state performance.
  6. Report the comparison transparently. State feedstock origin, upgrading, methane-leakage assumptions, electricity and heat inputs, capture coverage, functional unit, direct-versus-lifecycle boundary, and any allocation credits. Use a consistent lifecycle method before comparing alternatives.
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How should a footprint claim be checked?

For a useful comparison, ask what the number includes and what it leaves out. A claim should identify the feedstock pathway, methane losses and upgrading energy, reformer efficiency, heat supply, captured streams, and treatment of coproduct or recycling credits. It should also say whether it reports direct plant emissions or a lifecycle result, and use the same functional unit and accounting boundary across alternatives.

The 2016 indexed biogas LCA record does not provide enough methodological detail here for a rigorous like-for-like comparison, and the 2024 UK and EU publications have distinct regulatory and geographic scopes. A site-specific assessment therefore needs local feedstock data, measured methane losses, plant energy and emissions data, and an explicitly consistent lifecycle method.

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